VALORACIÓN DE ACETINAS COMO REEMPLAZO PARCIAL DE ACEITE NAFTÉNICO EN COMPUESTOS DE CAUCHO SBR1502

Autores/as

DOI:

https://doi.org/10.18041/1909-2458/ingeniare.28.6082

Palabras clave:

Acetinas, Compuestos, Entrecruzamiento, Esterificación, Glicerina, SBR

Resumen

En esta investigación, glicerina grado técnico proveniente de la industria del biodiesel se esterificó para obtener mono, di, tri acetil gliceroles. Se empleo ácido acético glacial y resina de intercambio iónico Amberlyst®15 como catalizador heterogéneo para llevar a cabo la reacción. Acetil gliceroles fueron probados para reemplazar parcialmente hasta 10 partes en peso de aceite nafténico en formulaciones de caucho SBR1502 reforzado con sílica precipitada. Se uso peróxido de dicumilo para curar los compuestos. Se realizaron ensayos de reometría a los compuestos antes de ser curados. La resistencia a la tracción, elongación a rotura y resistencia al desgarre fueron evaluados para los compuestos curados. Se determinó que la adición de 10 phr de acetil gliceroles afectó levemente el torque mínimo y la resistencia a la tracción.

Descargas

Los datos de descarga aún no están disponibles.

Referencias

E. Kaya and N. Oktar. (2019).Production of value-added chemicals from esterification of waste glycerol over MCM-41 supported catalysts.Green Process Synth. 8(1), pp. 128–134.https://doi.org/10.1515/gps-2018-0034

H.W. Tan, A.R. Aziz, and M. Aroua. (2013). Glycerol production and its applications as a raw material : A review. Renewable and Sustainable Energy Reviews.27, pp. 118–127. https://doi.org/10.1016/j.rser.2013.06.035

A. Rodrigues, J. C. Bordado, and R. G. Dos Santos. (2017). Upgrading the glycerol from biodiesel production as a source of energy carriers and chemicals -A technological review for three chemical pathways. Energies.10 (11), pp. 1–36. https://doi.org/10.3390/en10111817

M. Sinaga, G. Rico, A. Nababan, and T. Manullang. (2018). Effect of solvent volume ratio and time extraction of glycerol purification. Mater. Sci. Eng. 309 (1), pp. 1–6. https://doi.org/10.1088/1757-899X/309/1/012123

C.G. Chol, R. Dhabhai, A. Dalai, and M. Reaney. (2018). Purification of crude glycerol derived from biodiesel production process: Experimental studies and techno-economic analyses. Fuel Process. Technol. 178 (May), pp. 78–87. https://doi.org/10.1016/j.fuproc.2018.05.023

I. Contreras, E. Avella, J. Sierra, C. Guerrero, and J. Sodré. (2015). Purification of glycerol from biodiesel production by sequential extraction monitored by 1H NMR. Fuel Process. Technol. 132, pp. 78–87. https://doi.org/ 10.1016/j.fuproc.2014.12.016

M. Nanda, Z. Yuan, W. Qin, M. Poirier, and X. Chunbao. (2014). Purification of Crude Glycerol using Acidification: Effects of Acid Types and Product Characterization. Austin Chemical Engineering. 1(1), pp. 1–7. www.austinpublishinggroup.com

F. Cardeño, L. J. Gallego, and L.A. Rios. (2011). Refinación de la fase glicerina del biodiesel de aceite de palma empleando ácidos minerales. Información Tecnológica. 22 (6), pp. 15–24. https://doi.org/10.4067/S0718-07642011000600003

J. Hernández, J. Acevedo, C. Valdés, and F. Posso. (2015). Evaluation of using alternative routes of glycerin obtained in the biodiesel production: a review. Ingeniería y Desarrollo. 33 (1), pp. 126–148. https://doi.org/10.14482/inde.33.1.5573

Z. Ishak, N. Sairi, Y. Alias, M. Aroua, and R. Yusoff. (2016). Production of glycerol carbonate from glycerol with aid of ionic liquid as catalyst. Chem. Eng. J. 297, pp. 128–138. https://doi.org/10.1016/j.cej.2016.03.104

P. Okoye, A. Abdullah, and B. Hameed. (2017). Synthesis of oxygenated fuel additives via glycerol esterification with acetic acid over bio-derived carbon catalyst. Fuel. 209 (July), pp. 538–544. https://doi.org/10.1016/j.fuel.2017.08.024

S. Kale, S. Umbarkar, M. Dongare, R. Eckelt, U. Armbruster and A. Martin. (2015). Selective formation of triacetin by glycerol acetylation using acidic ion-exchange resins as catalyst and toluene as an entrainer. Appl. Catal. A Gen. 490, pp. 10–16. https://doi.org/10.1016/j.apcata.2014.10.059

M. Aghbashlo, M. Tabatabaei, H. Jazini, and H. Ghaziaskar. (2018). Exergoeconomic and exergoenvironmental co-optimization of continuous fuel additives (acetins) synthesis from glycerol esterification with acetic acid using Amberlyst 36 catalyst. Energy Convers. Manag. 165 (January), pp. 183–194. https://doi.org/10.1016/j.enconman.2018.03.054

A. Cornejo, I. Barrio, M. Campoy, J. Lázaro, and B. Navarrete. (2017). Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review. Renew. Sustain. Energy Rev. 79 (November), pp. 1400–1413. https://doi.org/10.1016/j.rser.2017.04.005

I. Banu, G. Bumbac, D. Bombos, S. Velea, A. Gălan, and G. Bozga. (2020). Glycerol acetylation with acetic acid over Purolite CT-275. Product yields and process kinetics. Renew. Energy. 148, pp. 548–557. https://doi.org/10.1016/j.renene.2019.10.060

B. Dalla, H. Decolatti, M. Legnoverde, and C. Querini. (2017). Influence of acidic properties of different solid acid catalysts for glycerol acetylation. Catalysis Today. 289, pp. 222–230. https://doi.org/10.1016/j.cattod.2016.09.015

D.M. Reinoso and G.M. Tonetto. (2018). Bioadditives synthesis from selective glycerol esterification over acidic ion exchange resin as catalyst. J. Environ. Chem. Eng. 6 (2), pp. 3399–3407. https://doi.org/10.1016/j.jece.2018.05.027

I. Franta. Elastomers and Rubber Compounding Materials. 1 Ed. Praga. Czechoslovakia. Elseiver. 1989.

J.R. White, S.K. De. Rubber Technologist’s Handbook . 1 Ed. Shawbury. United Kingdom. Rapra Publishers. 2001.

A. Puşcă, Ş. Bobancu. A. Duţă. (2001) Mechanical Properties of Rubber - An Overview. Bulletin of the Transilvania University of Braşov. 3 (52), pp. 107-114.

J.S. Dick. Rubber Technology. Compounding and Testing for Performance. 2 Ed. Munich. Germany. Hanser Publishers. 2004.

J.S. Dick. Basic Rubber Testing: Selecting Methods for a Rubber Test Program. 1 Ed. New York. USA. ASTM. 2004.

Descargas

Publicado

2020-05-10

Número

Sección

Artículos

Cómo citar

1.
VALORACIÓN DE ACETINAS COMO REEMPLAZO PARCIAL DE ACEITE NAFTÉNICO EN COMPUESTOS DE CAUCHO SBR1502. ingeniare [Internet]. 2020 May 10 [cited 2025 Feb. 23];(28):23-3. Available from: https://revistas.unilibre.edu.co/index.php/ingeniare/article/view/6082